Direct Methane to Methanol: Foundations and Prospects of the by Vladimir Arutyunov

By Vladimir Arutyunov

Direct Methane to Methanol: Foundations and customers of the Process bargains a cutting-edge account of 1 of the main fascinating and most likely advertisement applied sciences for direct conversion of typical gasoline into helpful chemical compounds. The booklet completely explains the complicated and strange chemistry of the method, in addition to attainable functions for direct methane to methanol (DMTM). It covers themes concerning thermokinetics, strain, direct oxidation of heavier alkanes, and extra, and gives exact appendices with experimental facts and product yields.

This booklet offers all those that paintings within the box of fuel processing and gasoline chemistry with the idea and experimental facts to increase and follow new strategies in line with direct oxidation of typical gasoline. All those that care for oil and common gasoline creation and processing will know about this promising expertise for the conversion of gasoline into extra precious chemical compounds.

  • Reviews greater than 350 courses on high-pressure, low-temperature oxidation of methane and different fuel section hydrocarbons
  • Contains infrequent fabric on hand for the 1st time in English
  • Explains the explanations of past failure and descriptions the future of advertisement improvement of the conversion technology
  • Presents a deep theoretical wisdom of this complicated conversion process

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Extra resources for Direct Methane to Methanol: Foundations and Prospects of the Process

Sample text

The CH3OH/CH2O ratio increased almost linearly with the pressure (Fig. 7); at the same pressure and residence time, it was about an order of magnitude higher than that reported in [69] (Fig. 9). Most likely, this is due to a higher rate of CH2O loss on the 32 3. 5 Yield of CH3OH as a function of the pressure in the static reactor at T ¼ 350  C and CH4/O2 ¼ 9:1 [15]. 0 s. Based on the data from [51]. 8 s. Based on the data from [51]. EFFECT OF PRESSURE ON THE YIELD OF THE PARTIAL METHANE OXIDATION PRODUCTS 33 Pressure dependence of the (C) total yield of liquid organic products, (-) total selectivity of formation of liquid organic products, (:) concentration of methanol in liquid product, and (A) concentration of the sum of aldehydes.

8%. [69]. Pressure dependence of the total yield of liquid oxidation products at T ¼ 400  C and products, as in a number of experiments performed in [46], there was a clear predominance of CO2 over CO. Of the oxygenates, along with methanol and formaldehyde, trace amounts HCOOH, C2H5OH, and CH3COCH3 were also detected. It is interesting that, after the reaction essentially stopped, 20% of the oxygen remained unreacted. 8%: (-) H2O, (:) CH3OH, and (C) CH2O [69]. 17% at 3400 atm (Appendix I). Thus, the behaviour of the DMTM process at extreme pressure does not show any specific features in the kinetic characteristics or in the composition of the products, contrary to the assumptions on the possibility of the cage effect under these conditions [79].

9). Most likely, this is due to a higher rate of CH2O loss on the 32 3. 5 Yield of CH3OH as a function of the pressure in the static reactor at T ¼ 350  C and CH4/O2 ¼ 9:1 [15]. 0 s. Based on the data from [51]. 8 s. Based on the data from [51]. EFFECT OF PRESSURE ON THE YIELD OF THE PARTIAL METHANE OXIDATION PRODUCTS 33 Pressure dependence of the (C) total yield of liquid organic products, (-) total selectivity of formation of liquid organic products, (:) concentration of methanol in liquid product, and (A) concentration of the sum of aldehydes.

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